N-(2-Amino-4,6-dihydroxypyrimidin-5-yl)acetamide dihydrate

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N-(2-Amino-4,6-dihydroxypyrimidin-5-yl)acetamide dihydrate

The title compound, C(6)H(8)N(4)O(3)·2H(2)O, which crystallized as a dihydrate, has two almost planar segments viz. the pyrimidine ring and the C-N-C(=O)-C group [maxmum deviations of 0.020 (2) and 0.014 (2) Å, respectively], with a dihedral angle of 87.45°. In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds.

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In the title compound, 2C(5)H(6)BrN(2) (+)·C(4)H(2)O(4) (2-)·2H(2)O, the complete fumarate dianion is generated by crystallographic inversion symmetry. The cation is approximately planar, with a maximum deviation of 0.036 (1) Å. In the anion, the carboxyl-ate group is twisted slightly away from the attached plane; the dihedral angle between carboxyl-ate and (E)-but-2-ene planes is 6.11 (14)°. I...

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In the title compound, C(12)H(16)N(6)O(2)·2H(2)O, the organic mol-ecule, except for the methyl H atoms, is essentially planar, the r.m.s. deviation from planarity being 0.044 Å. The crystal structure is stabilized by inter-molecular O-H⋯O and O-H⋯N hydrogen bonds which form chains.

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There are two 5-amino-1,3,4-thia-diazole-2(3H)-thiolate anions in the asymmetric unit of the title compound, Na(+)·C(2)H(2)N(3)S(2) (-)·2H(2)O, which are almost perpendicular to each other [dihedral angle = 84.64 (6)°]. The two Na(+) cations are in distorted fourfold coordinations by O atoms of the water molecules. The crystal structure is stabilized by N-H⋯S, O-H⋯N and O-H⋯S hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811034441